10 research outputs found

    Method of continuously determining crack length

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    The determination of crack lengths in an accurate and straight forward manner is very useful in studying and preventing load created flaws and cracks. A crack length sensor according to the present invention is fabricated in a rectangular or other geometrical form from a conductive powder impregnated polymer material. The long edges of the sensor are silver painted on both sides and the sensor is then bonded to a test specimen via an adhesive having sufficient thickness to also serve as an insulator. A lead wire is connected to each of the two outwardly facing silver painted edges. The resistance across the sensor changes as a function of the crack length in the specimen and sensor. The novel aspect of the present invention includes the use of relatively uncomplicated sensors and instrumentation to effectively measure the length of generated cracks

    Design and Comparison of Immersive Interactive Learning and Instructional Techniques for 3D Virtual Laboratories

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    This work presents the design, development, and testing of 3D virtual laboratories for practice, specifically in undergraduate mechanical engineering laboratories. The 3D virtual laboratories, implemented under two virtual environments3DTV and Computer Automated Virtual Environment (CAVE)serve as pre-lab sessions performed before the actual physical laboratory experiment. The current study compares the influence of two instructional methods (conventional lecture-based and inquiry-based) under two virtual environments, and the results are compared with the pre-lab sessions using a traditional paper-based lab manual. Subsequently, the evaluation is done by conducting performance and quantitative assessments from students pre-and post-laboratory performances. The research results demonstrate that students in the virtual modules (3DTV and CAVE) performed significantly better in the actual physical experiment than the students in the control group in terms of the overall experiment familiarity and procedure and the conceptual knowledge associated with the experiment. 2015 by the Massachusetts Institute of Technology

    Electrochemical detection of Cr(VI) and Cr(III) ions present in aqueous solutions using bio-modified carbon paste electrode: a voltammetric study

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    International audienceChromium is recognised as a potent water pollutant by the WHO and thus it becomes pertinent to continuously monitor chromium levels in the waterbodies. Voltammetry, an electroanalytical technique, has been utilised for the detection of hexavalent (Cr(VI)) and trivalent (Cr(III)) chromium in aqueous samples. Carbon Paste Electrode (CPE) modified using Sphingopyxis macrogoltabida SUK2c, an indigenous bacterial strain isolated from the water samples collected from Sukinda Valley, Odisha, India, was used as a working electrode in a typical three-electrode electrochemical cell. The developed biosensors were found to provide about 3.5 fold increase in cathodic peak current compared to the bare CPE for Cr(VI) ions. Using cyclic voltammetry (CV), the Lowest Limit of Detection (LLOD) of 1 x 10(-4) M and 1 x 10(-2) M for Cr(VI) and Cr(III) ions, respectively, were achieved with the biosensors. The LLOD was further improved to 1 x 10(-9) M and 1 x 10(-7) M for Cr(VI) and Cr(III) ions, respectively, adopting differential pulse cathodic stripping Vvoltammetry (DPCSV) technique employing the biosensors. The concentrations of Cr(VI) and Cr(III) ions present in water samples collected from Sukinda Valley, Odisha, India, could be determined using the biosensor. The plausible mechanisms involved in the detection of Cr(VI) and Cr(III) ions by the developed electrochemical biosensor are discussed.Keyword

    Utility of Chromobacterium violaceum SUK1a, an indigenous bacterial isolate for the bioremediation of Cr(VI)

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    The potential of an indigenous bacterial strain, Chromobacterium violaceum SUK1a, isolated from surface water samples collected from Sukinda Valley in Odisha, India, has been evaluated for the first time for the bioremediation of toxic hexavalent chromium (Cr(VI)) ions. The isolate was assessed for its Cr(VI) biosorption efficiency and the various parameters affecting the biosorption process were evaluated. A maximum Cr(VI) biosorption of about 50% was obtained, and the residual chromium was in the form of less toxic Cr(III). The Gibbs free energy of biosorption was determined to be -26.3 kJ/mol, suggestive of a chemisorption process. Additionally, the Cr(VI) biosorption by the isolate followed pseudo second order kinetics. FTIR spectral studies indicated that the surface functional groups present on the bacterial isolate such as, carboxyl, hydroxyl, amino, and phosphate groups were involved in the complexation of chromium ions with the bacterial cells. X-ray photoelectron spectroscopic studies on Cr(VI) interacted bacterial cells revealed an additional peak corresponding to Cr(III) in the Cr(2p) spectra. The surface charge of the bacterial cells subsequent to interaction with Cr(VI) were less negative compared to the pristine cells, which further substantiated the bioreduction of Cr(VI) to Cr(III). The bioremediation mechanism of Cr(VI) by the bacterial isolate is delineated to be governed by both biosorption and bioreduction processes under metabolism independent conditions. The results obtained indicate that the isolate can be a promising candidate for Cr(VI) bioremediation applications

    The Stability of Cyclodextrin Complexes in Solution

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